The δ60/58Ni Values of Twenty‐Six Selected Geological Reference Materials     

Weihan Li  Jian‐Ming Zhu  Decan Tan  Guilin Han  Zhouqiao Zhao  Guangliang Wu 《Geostandards and Geoanalytical Research》2020,44(3):523-535

The high‐precision δ^60/58Ni values of twenty‐six geological reference materials, including igneous rocks, sedimentary rocks, stream sediments, soils and plants are reported. The δ^60/58Ni values of all samples were determined by double‐spike MC‐ICP‐MS (Nu Plasma III). Isotope standard solution (NIST SRM 986) and geological reference materials (BHVO‐2, BCR‐2, JP‐1, PCC‐1, etc.) were used to evaluate the measurement bias and intermediate precision over a period of six months. Our results show that the intermediate precision of Ni isotope determination was 0.05‰ (2s, n = 69) for spiked NIST SRM 986 and typically 0.06‰ for actual samples, and the δ^60/58Ni _{NIST SRM 986} values were in excellent agreement with previous studies. Eighteen high‐precision Ni isotope ratios of geological reference materials are first reported here, and their δ^60/58Ni values varied from ?0.27‰ to 0.52‰, with a mean of 0.13 ± 0.34‰ (2s, n = 18). Additionally, SGR‐1b (0.56 ± 0.04‰, 2s), GSS‐1 (?0.27 ± 0.06‰, 2s), GSS‐7 (?0.11 ± 0.01‰, 2s), GSD‐10 (0.46 ± 0.06‰, 2s) and GSB‐12 (0.52 ± 0.06‰, 2s) could potentially serve as candidate reference materials for Ni isotope fractionation and comparison of Ni isotopic compositions among different laboratories.  相似文献   

A feasible approach to predicting time-dependent bearing performance of jacked piles from CPTu measurements     

Li  Lin  Li  Jingpei  Sun  De’an  Gong  Weibing 《Acta Geotechnica》2020,15(7):1935-1952

Acta Geotechnica - In this paper, a simple but feasible approach is proposed to predict the time-dependent load carrying behaviours of jacked piles from CPTu measurements. The corrected cone...  相似文献   

多向不规则波浪作用下群墩结构上爬高的计算研究     

季新然  邹丽  任智源  柳淑学 《海洋学报》2019,41(3):35-43

波浪的方向分布对波浪的传播及其与工程结构物的作用都具有明显影响，目前现有的研究大多是基于单向波浪进行的。为了研究方向分布对群墩结构上的爬高影响，基于规则波浪与群墩作用的理论解，结合多向不规则波浪的造波方法，建立了多向不规则波浪与群墩作用的计算模型，同时进行了物理模型试验对模型的有效性进行了验证。系统地对群墩周围及表面上的波浪爬高进行了计算分析，结果表明，方向分布对波浪爬高具有较大的影响，且不同位置处的影响并不相同，在实际的工程设计中如果按照单向波浪计算，可能低估或者高估群墩周围的爬高。  相似文献   

Calibration method affects the measured δ2H and δ18O in soil water by direct H2Oliquid–H2Ovapour equilibration with laser spectroscopy     

Hongxiu Wang  Bingcheng Si  Dyan Pratt  Han Li  Xiaojun Ma 《水文研究》2020,34(2):506-516

The direct H₂O_liquid–H₂O_vapour equilibration method utilizing laser spectroscopy (DVE-LS) is a way to measure soil pore water stable isotopes. Various equilibration times and calibration methods have been used in DVE-LS. Yet little is known about their effects on the accuracy of the obtained isotope values. The objective of this study was to evaluate how equilibration time and calibration methods affect the accuracy of DVE-LS. We did both spiking and field soil experiments. For the spiking experiment, we applied DVE-LS to four soils of different textures, each of which was subjected to five water contents and six equilibration times. For the field soil experiment, we applied three calibration methods for DVE-LS to two field soil profiles, and the results were compared with cryogenic vacuum distillation (CVD)-LS. Results showed that DVE-LS demonstrated higher δ²H and δ¹⁸O as equilibration time increased, but 12 to 24 hr could be used as optimal equilibration time. For field soil samples, DVE-LS with liquid waters as standards led to significantly higher δ²H and δ¹⁸O than CVD-LS, with root mean square error (RMSE) of 8.06‰ for δ²H and 0.98‰ for δ¹⁸O. Calibration with soil texture reduced RMSE to 3.53‰ and 0.72‰ for δ²H and δ¹⁸O, respectively. Further, calibration with both soil texture and water content decreased RMSE to 3.10‰ for δ²H and 0.73‰ for δ¹⁸O. Our findings conclude that the calibration method applied may affect the measured soil water isotope values from DVE-LS.  相似文献   

Dissolved organic matter in surface runoff in the Loess Plateau of China: The role of rainfall events and land-use     

Zhongwu Li  Hao Peng  Binggeng Xie  Chun Liu  Xiaodong Nie  Danyang Wang  Mei Huang  Haibing Xiao  Lin Shi  Xuqin Zhang  Jieyu Jiang 《水文研究》2020,34(6):1446-1459

Exploring the chemical characterization of dissolved organic matter (DOM) is important for understanding the fate of laterally transported organic matter in watersheds. We hypothesized that differences in water-extractable organic matter (WEOM) in soils of varying land uses and rainfall events may significantly affect the quality and the quantity of stream DOM. To test our hypotheses, characteristics of rainfall-runoff DOM and WEOM of source materials (topsoil from different land uses and gullies, as well as typical vegetation) were investigated at two adjacent catchments in the Loess Plateau of China, using ultraviolet–visible absorbance and excitation emission matrix fluorescence with parallel factor analysis (PARAFAC). Results indicated that land-use types may significantly affect the chemical composition of soil WEOM, including its aromaticity, molecular weight, and degree of humification. The PARAFAC analysis demonstrated that the soils and stream water were dominated by terrestrial/allochthonous humic-like substances and microbial transformable humic-like fluorophores. Shifts in the fluorescence properties of stream DOM suggested a pronounced change in the relative proportion of allochthonous versus autochthonous material under different rainfall patterns and land uses. For example, high proportions of forestland could provide more allochthonous DOM input. This study highlights the relevance of soils and hydrological dynamics on the composition and fluxes of DOM issuing from watersheds. The composition of DOM in soils was influenced by land-use type. Precipitation patterns influenced the proportion of terrestrial versus microbial origins of DOM in surface runoff. Contributions of allochthonous, terrestrially derived DOM inputs were highest from forested landscapes.  相似文献   

How soil texture,channel shape and cross-sectional area affect moisture dynamics and water loss in irrigation channels     

Zhifan Mu  Tianxiao Li  Dong Liu  Qiang Fu  Renjie Hou  Qinglin Li  Yi Ji  Song Cui  Mo Li 《水文研究》2021,35(4):e14155

To enhance the utilization efficiency of farmland irrigation water and reduce the leakage of water conveyance channels, the leakage process of channels was simulated dynamically. The simulated results were compared with data measured in laboratory experiments, and the performance of the model was evaluated. The results indicated that the simulated values of the model were consistent with the observation values, and the R² values varied between 0.91 and 0.99. In addition, based on the laboratory experiments, a water supply system (Mariotte bottles) and soil box were built using plexiglass. Three influencing factors, namely, the channel form, soil texture and channel cross-sectional area, were varied to observe and calculate the resulting cumulative infiltration amount, infiltration rate and wetting front migration distance. HYDRUS-3D software was used to solve the three-dimensional soil water movement equation under different initial conditions. The results demonstrated that the U-shaped channel was more effective than the trapezoidal channel in increasing the utilization efficiency of the water resources. A U-shaped channel with a small channel cross-sectional area should be adopted and the soil particle size should be prioritized in the construction of water conveyance channels for farmlands. The simulation results were in agreement with the observed results, which indicates that HYDRUS-3D is a reliable tool that can accurately simulate the soil moisture movement in water conveyance channels. The research results can provide a reference for the design and operation of farmland irrigation systems.  相似文献   

Response of soil aggregate disintegration to the different content of organic carbon and its fractions during splash erosion     

Hairu Li  Gang Liu  Ju Gu  Hong Chen  Hongqiang Shi  Mohamed A. M. Abd Elbasit  Feinan Hu 《水文研究》2021,35(2):e14060

Aggregate disintegration is a critical process in soil splash erosion. However, the effect of soil organic carbon (SOC) and its fractions on soil aggregates disintegration is still not clear. In this study, five soils with similar clay contents and different contents of SOC have been used. The effects of slaking and mechanical striking on splash erosion were distinguished by using deionized water and 95% ethanol as raindrops. The simulated rainfall experiments were carried out in four heights (0.5, 1.0, 1.5 and 2.0 m). The result indicated that the soil aggregate stability increased with the increases of SOC and light fraction organic carbon (LFOC). The relative slaking and the mechanical striking index increased with the decreases of SOC and LFOC. The reduction of macroaggregates in eroded soil gradually decreased with the increase of SOC and LFOC, especially in alcohol test. The amount of macroaggregates (>0.25 mm) in deionized water tests were significantly less than that in alcohol tests under the same rainfall heights. The contribution of slaking to splash erosion increased with the decrease of heavy fractions organic carbon. The contribution of mechanical striking was dominant when the rainfall kinetic energy increased to a range of threshold between 9 J m⁻² mm⁻¹ and 12 m⁻² mm⁻¹. This study could provide the scientific basis for deeply understanding the mechanism of soil aggregates disintegration and splash erosion.  相似文献   

Burial and exhumation of the Hoh Xil Basin,northern Tibetan Plateau: Constraints from detrital (U-Th)/He ages     

Jin-Gen Dai  Matthew Fox  David L. Shuster  Jeremy Hourigan  Xu Han  Ya-Lin Li  Cheng-Shan Wang 《Basin Research》2020,32(5):894-915

The uplift and associated exhumation of the Tibetan Plateau has been widely considered a key control of Cenozoic global cooling. The south-central parts of this plateau experienced rapid exhumation during the Cretaceous–Palaeocene periods. When and how the northern part was exhumed, however, remains controversial. The Hoh Xil Basin (HXB) is the largest late Cretaceous–Cenozoic sedimentary basin in the northern part, and it preserves the archives of the exhumation history. We present detrital apatite and zircon (U-Th)/He data from late Cretaceous–Cenozoic sedimentary rocks of the western and eastern HXB. These data, combined with regional geological constraints and interpreted with inverse and forward model of sediment deposition and burial reheating, suggest that the occurrence of ca. 4–2.7 km and ca. 4–2.3 km of vertical exhumation initiated at ca. 30–25 Ma and 40–35 Ma in the eastern and western HXB respectively. The initial differential exhumation of the eastern HXB and the western HXB might be controlled by the oblique subduction of the Qaidam block beneath the HXB. The initial exhumation timing in the northern Tibetan Plateau is younger than that in the south-central parts. This reveals an episodic exhumation of the Tibetan Plateau compared to models of synchronous Miocene exhumation of the entire plateau and the early Eocene exhumation of the northern Tibetan Plateau shortly after the India–Asia collision. One possible mechanism to account for outward growth is crustal shortening. A simple model of uplift and exhumation would predict a maximum of 0.8 km of surface uplift after upper crustal shortening during 30–27 Ma, which is insufficient to explain the high elevations currently observed. One way to increase elevation without changing exhumation rates and to decouple uplift from upper crustal shortening is through the combined effects of continental subduction, mantle lithosphere removal and magmatic inflation.  相似文献   

华北克拉通南缘石炭系本溪组铁-铝黏土矿物质来源: 以河南三门峡大安铝黏土矿床为例^*          下载免费PDF全文

刘学飞  王庆飞  马遥  李中明  赵利华  周智慧  刘百顺  马欣莉 《古地理学报》2020,22(5):965-976

华北克拉通在中奥陶世至晚石炭世期间一直出露地表,经历了长期的风化作用,形成大规模的铁-铝黏土矿,其成矿物源一直是研究的热点,尤其是本溪组底部铁矿和铁质黏土矿与上部铝黏土矿是否为同一来源尚未查清。本研究选取克拉通南缘大安铝黏土矿床作为研究对象,展开微区矿物及元素地球化学组成分析,进一步探讨铁-铝黏土矿物质来源。大安矿床内含矿岩系自下而上包括铁质黏土岩、铝土矿、铝质黏土矿;局部喀斯特高地缺失铝土矿,铝质黏土矿直接覆盖于铁质黏土岩之上。铁质黏土岩在洼地以菱铁矿、黄铁矿和伊利石为主,在隆起区以赤铁矿、伊利石和高岭石为主。铝土矿以硬水铝石、伊利石和锐钛矿为主;铝质黏土矿主要矿物为伊利石。矿物微区分析在黏土矿底部发现大量的碳化硅和少量自然硅、硅铁矿、铬铁矿;区域对比揭示北秦岭造山带内商丹缝合带和二郎坪群中的蛇绿岩为铝黏土矿形成提供了成矿物质。本溪组底部铁质黏土与上部铝黏土矿稳定元素比率(例如Zr/TiO₂、Hf/TiO₂、Nb/TiO₂、Ta/TiO₂)存在明显差异,揭示二者为不同来源: 底部铁质黏土岩和铁矿层为底板碳酸盐岩原地风化的产物;而上部铝黏土矿是异地搬运物,北秦岭造山带在晚石炭世的整体抬升为华北铝黏土矿形成提供了重要的成矿物质。  相似文献   

Mineralogy,Fluid Inclusion,and Hydrogen and Oxygen Isotope Studies of the Intrusion‐Related Yangla Cu Deposit in the Sanjiang Region,SW China: Implications for Metallogenesis and Deposit Type     

Li‐Juan Du  Bo Li  Zhi‐Long Huang  Jun Chen  Jia‐Xi Zhou  Guo‐Fu Zou  Zai‐Fei Yan 《Resource Geology》2020,70(1):28-49

The Yangla deposit is an intrusion‐related Cu deposit in the Jinshajiang tectonic belt (eastern Sanjiang region, SW China). Despite extensive studies that have been conducted on this deposit, the relationship between the granitic magma and Cu mineralization is still unclear, and hence, the genesis is debated. To answer this question, we conducted an integrated study of mineralogy, fluid inclusions (FIs), and hydrogen and oxygen (H‐O) isotopes. Three mineralization stages were identified based on the ore textures, alteration zonation, and crosscutting relationships: (i) pre‐ore prograde skarn (stage I), with the garnet and pyroxene dominated by andradite and diopside, respectively; (ii) syn‐ore retrograde alteration (stage II), which is subdivided into the early syn‐ore stage (stage IIa) marked by retrograde hydrated mineral assemblages and significant Fe‐Cu‐Mo‐Pb‐Zn sulfide mineralization, and the late syn‐ore stage (stage IIb) featured by quartz‐calcite veins; and (iii) late supergene mineralization (stage III), which is characterized by secondary azurite and malachite. These results of mineralogy, FIs, and H‐O isotopes indicate that: (i) Cu mineralization has a close temporal, spatial, and genetic relationship with skarn alteration; (ii) the ore fluids were magmatic dominated with late‐stage meteoric water incursion; and (iii) Type‐S (halite‐bearing) and Type‐V (vapor‐rich) FIs coexisted in garnet and clinopyroxene of stage I, indicating that fluid boiling might have occurred during this stage. From stage I to stage IIa, the FI type transformed from Type‐S + Type‐V + Type‐L (liquid‐rich) to Type‐V + Type‐L with the conduct of mineralization and was accompanied by the disappearance of Type‐S, and homogenization temperature and salinity also tended to decrease dramatically, which may be caused by the deposition of skarn minerals. At stage IIa, boiling of the ore fluids still continued due to the change from lithostatic to hydrostatic pressure, which triggered the precipitation of abundant quartz‐Cu‐Mo‐Fe sulfides. Furthermore, fluid mixing between a high‐temperature magmatic fluid and a low‐temperature meteoric water might cause a considerable drop in temperature and the deposition of Cu‐bearing quartz/calcite veins during stage IIb. Hence, we consider the Yangla deposit to be of a skarn type, genetically related to the Mesozoic magmatism in the Sanjiang region.  相似文献